Dichloridobis(2-dimethylamino-1,10-phenanthroline)cadmium(II)
نویسنده
چکیده
In the title complex, [CdCl(2)(C(14)H(13)N(3))(2)], the Cd(II) ion lies on a twofold rotation axis and assumes a distorted octa-hedral CdN(4)Cl(2) coordination geometry. There is a π-π stacking inter-action between the symmetry-related 1,10-phenanthroline ligands with a centroid-centroid distance of 3.5578 (16) Å and a perpendicular distance of 3.445 (su?) Å between the relevant rings.
منابع مشابه
catena-Poly[[aqua(1,10-phenanthroline)cadmium(II)]-μ-benzene-1,4-dicarboxylato]
The title compound, [Cd(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)](n), is a new coordination polymer of benzene-1,4-dicarboxyl-ate with cadmium(II) and 1,10-phenanthroline. The Cd(II) ion is coordinated by two N atoms from the 1,10-phenanthroline mol-ecule, three O atoms from two crystallographically independent benzene-1,4-dicarboxyl-ate ligands and the O atom of a coordinated water mol-ecule, formi...
متن کاملcis-Dichloridobis(1,10-phenanthroline)chromium(III) chloride
In the title complex, [CrCl(2)(C(12)H(8)N(2))(2)]Cl, the Cr(III) ion is situated on a twofold rotation axis and displays a slightly distorted octa-hedral CrCl(2)N(4) coordination geometry. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline and two chloride ligands. The chloride counter-anion exhibits half-occupation and is equally disordered over two positions.
متن کاملDi-μ-acetato-κ3 O,O′:O;κ3 O:O,O′-bis[(acetato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cadmium(II)]
The title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(8)N(2))(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single π-π inter-action between...
متن کامل[(Nitrato-κ2 O,O′)(nitrito-κ2 O,O′)(0.25/1.75)]bis(1,10-phenanthroline-κ2 N,N′)cadmium(II)
The reaction of cadmium nitrate and sodium nitrite in the presence of 1,10-phenanthroline yields the mixed nitrate-nitrite title complex, [Cd(NO(2))(1.75)(NO(3))(0.25)(C(12)H(8)N(2))(2)]. The metal ion is bis-chelated by two N-heterocycles as well as by the nitrate/nitrite ions in a distorted dodeca-hedral CdN(4)O(4) coordination environment. One nitrite group is ordered; the other is disordere...
متن کاملcatena-Poly[[(2,9-diethoxy-1,10-phenanthroline-κ2 N,N′)cadmium(II)]-di-μ-dicyanamido-κ4 N 1:N 5]
In the title polymer, [Cd(C(2)N(3))(2)(C(16)H(16)N(2)O(2))](n), the Cd(II) ion is coordinated by two N atoms from one 2,9-dieth-oxy-1,10-phenanthroline mol-ecule and four N atoms from four symmetry-related dicyanamide ions in a distorted octa-hedral geometry. In the 2,9-dieth-oxy-1,10-phenanthroline ligand, the O and C atoms of the eth-oxy groups are located almost in the plane defined by the p...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009